BPG Media Problems

From Wiki

Characteristics inherent in graphic media which create problems: in the media or in the relationship between media and support; at time of application or as the object ages; or pose special problems during conservation treatment.

Original Compiler: Nancy Ash
For a full list of the original contributors to this page, see the section below on History of This Page below.
Wiki Contributors: Jennifer Evers, Terra Huber, Emily Williams, your name could be here

Copyright 2020. The Book and Paper Group Wiki is a publication of the Book and Paper Group of the American Institute for Conservation. It is published as a convenience for the members of the Book and Paper Group. Publication does not endorse nor recommend any treatments, methods, or techniques described herein. Please follow these instructions for citing the BPG Wiki, keeping in mind that the Wiki is a work in progress and is frequently updated. The BPG Wiki coordinators can be reached at [email protected].

Purpose


To identify potential problems so that treatment and storage and exhibition conditions can be limited or modified so that media are not altered. To identify problems to help determine treatment methods.

Factors to Consider


Inherent physical characteristics of media

  • Color
  • Surface: glossy or matte, compacted or fluffy
  • Topography: raised or flat, thick or thin
  • Integrity: fixed or loose, flexible or brittle (tented, flaking, etc.)


Relation of media to support

  • Media may discolor or degrade paper (e.g. oil paint, iron gall ink, printing ink, titanium dioxide, copper greens, zinc white).
  • Media may protect paper: lead and calcium whites; opaque pigments
  • Is media well adhered to paper support? (or to ground or underlying layers)


Alteration of media upon aging

  • Desiccation of binders: watercolor, gouache, tempera, distemper, printers inks
  • Oxidation of oils, waxes
  • Color changes, fading and other alterations may occur without the influence of an outside agent, e.g. fading of iron gall ink; felt tip pen inks.
  • Materials in combination with each other may cause changes over time, e.g. lead and arsenic containing pigments in Islamic miniatures. (M.C.)


Sensitivity of media to environment

  • Light: e.g. natural organic pigments, gamboge, cochineal lakes, indigo, carmine, vermillion; some pastels. Inorganic pigments are much less susceptible.
  • Humidity
  • Pollution: e.g. red lead, white lead, naples yellow, smalt
  • Heat: e.g. wax


Chemical sensitivity to

  • pH
  • Acidity: (calcium carbonate, red lead, ultramarine). “Litmus” reactions seen in watercolors which have been in contact with acidic mats.
  • Alkalinity: In most cases it is organic pigments that change colour on deacidification due to changes in their molecular and electronic structure (logwood, carthamine, gamboge, litmus, tumeric, cochineal) (Daniels). (Also, Prussian blue, madder, chrome green, Hookers green, yellow lake, van dyke brown, gamboge, some pigments in Currier and Ives prints).
  • Oxidation/reduction: indigo, Prussian blue (develops irridescence)
  • Heavy metal ions (some transition metals in particular, e.g. Co, Cu, Fe, Mn, Zn) which may catalyze degradation of cellulose in presence of oxygen and moisture (Mairinger et. al.-p. 181) Specific pigments: e.g. TiO2, ZnS, ZnO, copper greens.


Potential alteration of media during handling flexing support, brushing, touching or covering surface.

Note: a uniform surface “abrasion” or polishing may be a positive sign of the good condition and normal aging of old master prints and drawings kept historically in albums. (M.C.)

Potential alteration of media during conservation treatment Effect of moisture, solvents, consolidants, buffers, weight and pressure, heat, air currents, static charge, lining.

Treatment may affect the chemical structure of the media without causing visible alteration at the time of treatment.

Materials and Equipment



See specific catalogue categories as referenced below.

Treating friable or soluble media
Special considerations for friable materials

Media Problems


Media problems will be discussed in terms of general problems, specific problems, suggested or ill-advised treatments, and/or traditional and contemporary formulations and applications.

Drawing Media

Some potential friability with most drawing media. Range from slight to marked friability, with sensitivity to abrasion or to any material capable of generating or holding static charge, e.g. plexiglas/ polyester film.

Dusting of soft pencil or other friable drawing media over the surface of a drawing often creates a grimey or smudged appearance and poses the problem of whether or not to dry clean. Careful consideration should be given to possible creation of “halo” effects around drawing lines before undertaking such treatment (See Surface Cleaning).

Metal Point (See: Ellis; Harding)

  • Medium: An anticipated and desirable tarnishing of the metal media to their characteristic colors.
  • Ground:
  • Friable and easily abraded (surface should be carefully protected)
  • Absorbs oils and fingerprints
  • Softens and stains readily with moisture
  • Susceptible to cracking (See Watercolor and gouache under Paints)
  • Treatment:
Caution with oxidative bleaches - can cause discoloration of the media.
Reductive bleaches may cause changes in tarnished (naturally oxidized) media.

Pencil

  • Graphite
Pronounced reflectivity of natural graphite could be adversely affected by wet treatment (?) (M.C.)
  • Indelible pencil
  • Visually is virtually identical to graphite pencil. Purple component bleeds out with slight moisture application and may also be solvent (acetone) sensitive.
  • Seen in German and Central European works, often in signatures. Some suggestion that it was used during WWII when graphite was in short supply. Also appears in some Picasso signatures, so caution with pencil signatures on contemporary prints.
  • Treatment: Test pencil drawings and signatures separately. Will not necessarily bleed with brief testing with water.
Colored dye may be pH sensitive and conservator can possibly minimize disfiguring aspect of bleeding dye by locally applying buffered solution.
Encountered in a sketch by Dufy. In treatment it turned purple but did not bleed in acetone. Conservator continued wash with a stronger solvent; rinsed with acetone. Purple was removed except in four heaviest downstrokes. These lessened with local application of methanol.
"Mephisto" is one current brand name.
  • Carbon pencil
  • Colored pencil
  • May be fugitive
  • May be water soluble (e.g. Prismcolor). If watercolor pencils have been blended into a design by applying water, care must be taken not to soften hard edges of lines not treated with water. E.g. Many Jackson Pollack drawings were only partially treated with water by the artist to make washes. (M.E.)
  • Often sensitive to or soluble in organic solvents.
  • Watercolor pencil
Looks like regular colored pencil, but feathers even in slight vapor as would be used for flattening. Used dry by Jackson Pollack along with regular colored pencils. Each color must be checked prior to treatment. (M.E.)

Charcoal

  • Extreme friability makes any treatment problematic. In addition, a drawing may be only partially fixed, the lower layer being fixed before the last application of charcoal. Must test for fixing throughout the drawing.
  • Resinous or sooty charcoals may be soluble in solvents.
  • Homemade/manufactured charcoals may have dye additives.


Chalks

  • Natural chalks
  • White: calcium carbonate (see watercolor below), lead carbonate, calcium sulphate, etc.
  • Black
  • Red: (iron oxide) Not susceptible to fading. May darken and/or dissolve upon wetting.
Water and some organic solvents will disperse smallest particles, move out binder yielding darker, cooler hue. (D.D.M.)
Turns yellowish orange on abrasion.
  • Fabricated chalks and pastels
  • Friability: Greatest natural media friability is encountered in pastels and charcoal. While pastels may be fixed by the artist, fixing is not generally recommended as a conservation treatment as it can alter the appearance of the media. (See cautions for drawing media below).
  • Binder: Gum tragacanth, the traditional binder, is attractive to insects and promotes mold growth. Cellulose ethers are now used instead.
  • Sensitivity to Light: e.g. Degas used a bright red violet; red component is a lake (morphology under crossed polars); this fades leaving deep cobalt blue on surface. (P.D.)
  • Oil Pastels
Can be damaging to paper due to oil content. Can be sensitive to organic solvents for the same reason.

Waxy Crayons ("Crayon" also an early term for chalk and pastel)

Likely solubility or softening of waxy binders in organic solvents (See Bleaching).

Litho Crayon

May be solvent sensitive.

China Marker

Red, black, white.
May be solvent sensitive, soluble.

Cautions for drawing media during Conservation Treatment in the relevant treatment pages:

  • float washing: potential compaction, movement of loose particles.
  • solubility of one component of a mixed pigment undetected during testing (e.g. gamboge in a green).
  • Fixatives applied to reduce natural friablity of media, especially pastels and charcoal. Generally not recommended conservation treatment for drawing media, expecially pastels, as application will alter the artist's aesthetic. Can cause compaction/ saturation of media and blending of colors, possibly altering color value and characteristic "fluffy" surface.
Fixatives may be absorbed into the paper and cause (J.K.):
  • discoloration and degradation products to be held in sheet
  • haloing
  • uneven aging of paper
Potential transfer if object placed face against surface (particularly pastel). If such treatment is necessary with friable drawing media place recto against smooth relatively frictionless (glass, glassine, silicone release) and weight to prevent movement. Repeated testing essential in treatment, as pressure, steam or moisture applied to verso may cause unanticipated transfer of media.
If possible treat vertically as with a Dutch strainer (J.K.)
Considerations for friable materials
  • Suction Table Treatments
Some conservators are wary of possible compaction of media or pulling of media into the paper, particularly fluffy pastel. Possible problem of pulling soluble media to the back of the artwork.
  • Electrostatic plate (Blythe):
Creates an electrostatic attraction between the pastel particles and their support through the use of an electrostatic stabilizing plate (elaborate….)
Presented as an alternative to several methods of fixing which potentially alter the appearance of pastels.

Ink

Black carbon inks

  • India ink
Shellac binder soluble in alcohol.
  • Sumi or Indian black carbon inks
Very water soluble.

Brown inks

Deteriorated iron gall ink on paper, exhibiting cracking and burn through to verso. Normal illumination.
Photo by Katherine Kelly.
Some brown inks are affected by hydrogen peroxide or other oxidizing agents. Necessitates particular caution when converting darkened lead whites on brown ink drawings.
Example above with transmitted light.
Photo by Katherine Kelly.
  • Iron gall ink
Can also be categorized as a "black" ink, the color after initial application and atmospheric oxidation. Generally fades to reddish brown, often eventually to pale yellowish brown due to decomposition products of carboxyphenolic acids which can no longer complex with the traces of metallic oxides remaining on the support (Talbot et. al.-p. 1)
Note: Some inks are pale from the start depending upon the recipe (J.K.)
  • May penetrate, deteriorate, corrode paper support due to its acidity. No certain method for stopping or reversing its effect on paper. Weakest areas should be reinforced on verso with Japanese tissue. Extensive deterioration may warrant lining.
  • May fade (Talbot, et.al.-p. 2)
  • Factors affecting fading
  • external factors: oxygen, humidity, light, pollution
  • internal factors: composition of the ink, nature of the support
  • high pH in aqueous deacidification can lighten lines, whether by fading or by increasing solubility is unclear. (M. C.)
  • Methods of making faded iron gall ink visible:
  • UV or IR
  • Regeneration: various solutions to reintroduce color.
Iron Gall Ink Image Gallery
Iron Gall Ink Bibliography
Iron Gall Ink: General Information
Reissland, Birgit and Judith Hofenk de Graaff. Condition Rating for Objects with Iron Gall ink ICN-Information Number 1, November 2001, Netherlands Institute for CulturalHeritage (ICN). (accessed 3/2018)
  • Visual rating system to categorize condition of object and aid in decision making concerning preservation.
Reissland, Birgit and Frank Ligterink. 2011. The Iron Gall Ink Website. Maintained by the Cultural Heritage Agency (Amsterdam, NL) (accessed 3/2018)
  • Contains detailed information, recipes, and a long list of references.
Iron Gall Ink Examination
Baker, Cathleen A. 1985. "A Comparison of Drawing Inks Using Ultraviolet and Infrared Examination Techniques." In Application of Science in Examination of Works of Art, ed. by Pamela A. England and Lambertus van Zelst, 159-163. Boston: Museum of Fine Art.
  • Iron gall ink and carbon black ink can be distinguished under IR illumination. IGI is faint, carbon-based inks are dark.
Tse, Season, Doug Goltz, Sherry Guild, Valeria Orlandini, Maria Trojan-Bedynski, Mary Richardson. 2009. "Effect of Aqueous Treatments on Nineteenth-Century Iron-Gall-Ink Documents: Assessment Using Hyperspectral Imaging .The Book and Paper Group Annual 28.
Iron Gall Ink Testing
Neevel, Johan G. 2009. "Application issues of the bathophenanthroline test for iron(II) ions." Restaurator.
Iron Gall Ink General Treatment
Albro, Sylvia, Julie l. Biggs, Claire Dekle, Mary Elizabeth Haude, Cyntia Karnes, and Yasmeen Khan. 2008. "Developing Guidelines for Iron-Gall Ink Treatment at the Library of Congress .The Book and Paper Group Annual 27.
  • Presents guidelines for treating paper documents with iron-gall ink. The guidelines consist of:
  • Examination form designed specifically for iron-gall ink on paper to supplement the primary record of treatment
  • Glossary that standardizes the terminology used in the examination form
  • Recommendations for micro-chemical and solubility testing
  • Flow charts, or “treatment trees”, to guide the decision-making process based on results obtained through examination and testing
  • Explanatory notes on the treatment options presented.
Connelly-Ryan, Cindy, et al. 2007. "Optimizing ink corrosion treatment protocols at the Library of Congress. In Edinburgh Conference Papers 2006, ed. Shulla Jaques. London: Institute of Conservation, 195-202.
Dekle, Claire and Mary Elizabeth Haude. 2008. "Iron-gall Ink Treatment at the Library of Congress: Old Manuscripts—New Tools .The Book and Paper Group Annual 27.
  • Practical application of the Albro et al. paper above.
Hofmann, Christa, Dubravka Jembrih-Simbürger, Manfred Schreiner, Rudolf Eichinger, Leopold Puchinger, Oliver Hahn, Ute Henniges, Antje Potthast, and Erna Pilch-Karrer. 2007. "To Treat or Not to Treat—That is the Question: Options for the Conservation of Iron-Gall Ink on Paper .The Book and Paper Group Annual 26.
Orlandini, Valeria. 2009. "Effect of Aqueous Treatments on Nineteenth-Century Iron-Gall-Ink Documents: Calcium Phytate Treatment--Optimization of Existing Protocols .The Book and Paper Group Annual 28.
Iron Gall Ink Nonaqueous Treatment
Titus, Sonja , Regina Schneller, Enke Huhsmann, Ulrike Hähner and Gerhard Banik. 2009. "Stabilising local areas of loss in iron gall ink copy documents from the Savigny estate." Restaurator.
  • This article discusses the treatment of letterpress copy books with iron gall ink using Berlin tissue pre-coated with gelatin, activated with limited moisture on a suction table. Gelatin was chosen over Klucel because of its stabilizing influence on iron gall ink.
  • Bistre
  • Sepia


Colored Inks and Washes

Red inks are frequently extremely soluble and difficult to consolidate sufficiently for wet treatment.

Writing inks (fountain pen inks)

May have solvent sensitive/ soluble somponents.
Blue/black writing inks (especially those used by Elie Nadelman) have often faded to brown. Original color can be detected under magnification where the edges of the black line are blue, as wicked out by paper fibers. Very water soluble. (M.E.)

Ballpoint pen inks

Extremely variable in makeup and reaction to treatment. The lubricant in the pen ink is an oil base material.
May have solvent soluble/ sensitive components.
Often soluble in alcohols. This factor may be useful for removing or diminishing accession numbers written on artworks in ball point pen.
Some formulations are quite fugitive.

Felt tip pen inks

Most formulations are extremely fugitive even when stored in the dark. Some recent formulations may be more stable.
May have solvent sensitive/ soluble components.

Cautions for drawing inks during conservation treatment:

See Washing and Bleaching.

Paints

Watercolor and gouache:

May be fugitive, either fading or changing color, in the presence of light (also, oxygen and water vapor) because of thinness of application, minimum of binder, and/or inclusion of dyes and other natural organic materials.

Often one component of a mixed pigment (e.g. gamboge in a green) will be more fugitive than the other, shifting the tonal balance of the pigment as it fades.

  • Pigments: See Synthetics below.
  • Binders (gum arabic, vegetable gums, dextrin, tragacanth)
"An understanding of specific pigment usage and pigment/binder relationships will aid the conservator in deciding whether a watercolor can be washed and in what solution" (Cohn-AIC-p. 39).
  • Continued solubility or sensitivity to water:
  • Continued solubility has a great deal to do with whether watercolors were drycake, moist cake or tube. Therefore, pre-nineteenth century watercolors are generally a lot less soluble, assuming the washes are thin. Thicker accents will be soluble. Later watercolors may be very safe too, but each color must be tested at its point of thickest application. pH changes can adversely affect solubility. (M.C.)
Rule of thumb: watecolors over 60 years old tend to be less water soluble.
  • Folk art, such as Pa. Dutch Fraktur, where the home made paint was pigments ground in cherry gum, remain so soluble (esp. red and yellow) it is a risk to even spray the painting with water (Weidner).
Primary documents also list other binders used in Frakturs and folk art. Extreme solubility of these pigments is not necessarily the rule, and moisture can often be used after careful testing. (J.K.)
  • Treatment: Might humidify prior to aqueous treatment for more even and complete wetting of watercolors, and to ease the shock to the media.
  • Sensitivity to or solubility in organic solvents:
  • Watercolor pigments which are truly soluble in water (as compared to “sensitive”) may be highly soluble in other polar solvents as well.
  • Thanka paintings: Yak fat is used as binder can be sensitive to naptha and toluene.
  • Friability, flaking, tenting
Integrity and permanence of the paint layer depend on the adhesiveness of the binding gum, characteristics of the paper support, thickness of the paint layer, and environmental influences.
  • "The most common cause of flaking paint is dehydration of the binding vehicle used in the original mixing of the paint. Binders such as egg, glue or gum can gradually lose their ability to hold the pigment particles together or to their support" (e.g. Islamic miniatures, medieval manuscript illuminations, grounds of metal point drawings, tempera, gouache). (Ellis-p.31)
  • If paper surface is not sufficiently absorbent, paint adhesion may be incomplete or insecure. Also, the thinner the paper support, the more it moves (e.g. paper with short woodpulp fibers), the smoother its surface, the greater the possiblity of flaking.
  • If the paint layer is thick as in gouache, it will be brittle and inflexible and will tend to crack with movement of the paper support.
  • Treatment: Even a stable watercolor can have friable elements which are not evident until aqueous treatment is begun. Surface tension of the water bath can pull off friable material. Suggestion that this can be alleviated with the addition of alcohol to the bath (approximately 10% solution). Caution: the alcohol may make float washing a bit more difficult.
  • Masking agents
"Masking agents that establish areas of reserved highlights through the principle of water repellency (as opposed to water resistance, the principle of other masking agents) are other substances that are affected by organic solvents. Often their presence can be detected only through a careful examination in strong raking light, yet they should always be of concern, as their removal could take with it residues of fragmented color films" (Cohn-AIC-p.40)

Tempera

  • Often problems with cracking and flaking.
  • Specific artists: Andrew Wyeth often did not follow a recipe - problems with cracking and flaking in his works. Paul Cadmus followed medieval recipe, and no such problems seem to occur (M.E.).

Oil

  • Incompatible with paper support. Causes oxidation of the paper: degrading, discoloring, embrittling. A halo of discoloration appears around the pigments, caused by oil which has bled out and oxidized the fibers. A heavily sized paper may be somewhat more resistant to the degrading effects of oil.
Note: Some artists have sought the halo effect, e.g. Picasso (C.B.)
  • Can become hard and brittle with age. As paper contracts and expands with temperature and humidity fluctuations "if the paint is applied to the paper too thickly there is a good chance the paint will become crackled and flake off. It is for this reason that it is often recommended that a thick oil painting on paper be mounted on a rigid support" (Weidner).
  • Specific artists: Degas successfully used oil paints which had been leached of much of their oil, “Peinture a 1'essence,” ground pigments in spirits. These works are often mistaken for gouache because of their matte surface and "dry" look.
  • Paper can become sensitive to alkali. (J.K.)
  • Thymol softens oil binder.
  • Treatments for drawings severely weakened by oil medium: (Advisable to consult a painting conservator or, better yet, a Painting Conservation Catalogue).
  • Solid mounting
  • Lining with Japanese tissue. (Haner et.al.)

Synthetics

  • Acrylics
  • Magna color: solvent based media (xylene)
  • Liquitex: water based media, but does not remain so when dry.
  • Alkyd resins
  • Casein
  • Synthetic laquers
  • Nitrocellulose based products
  • Laquer (Agateen)
  • Paint
  • Metallic paints and Phosphorescent paints


Pigments

(Information on causes of pigment discoloration taken in large part from paper by D. Evans. See bibliography).

  • Whites
  • Chalk (whiting)(lime white)(calcium carbonate):
Acids released from paper support when it is humidified or wetted by float washing may consume, diminish or discolor the white pigment. Tends to soften with water.
  • Lead white (flake white) (basic lead carbonate):
Drawing with lead white darkening
Generally darkens to gray, brown or black lead sulphide when in contact with sulphide pigments (e.g. vermillion) or when exposed to hydrogen sulphide in a polluted atmosphere. This discoloration occurs more readily in the presence of moisture and is favored by darkness.
May be oxidized back to a white pigment, lead sulphate, with dilute, slightly alkaline hydrogen peroxide (aqueous or ethereal).
Hydrogen peroxide for converting lead whites should not be used in acidic solution because remaining lead carbonate may be consumed by the acid.
Occasionally it is observed that converted lead whites “appear” to revert to a gray state. It is likely that initially only a thin film of the pigment had darkened to the sulphide and had been converted to the sulphate during treatment, and that it is the remaining lead carbonate which has reacted with hydrogen sulphide to form more of the darkened pigment.
Darkened lead whites cannot always be successfully converted to a white pigment. Lead which which has gone "completely" black seems most resistant. Application of hydrogen peroxide as an oxidizing agent may only turn such pigment pale gray, and at worst may make it disappear.
Occasionally a yellow or salmon-colored phase is seen. Such pigment seems readily converted to white with hydrogen peroxide application.
  • Lithopone (combination of barium and zinc whites). Can darken in the presence of iron. (E. Sayer)
  • Zinc white (Chinese white) (zinc oxide): Photosensitizer - reacts photochemically with paper. Loses covering power due to hydrolysis by alkalis.
  • Titanium dioxide: Photosensitizer.
  • Reds
  • Natural Alizarin (madder lake) (organic): Purpurin component is quite fugitive.
  • Synthetic alizarin (from aluminum hydrate treated with alkali):
Alkali sensitive.
  • Carmine: (cochineal) (organic):
Discolors to a greenish grey or a faint sepia-like brown in sunlight.
  • Cadmium red (inorganic):
Poisonous if ingested. Blackens in chemical reactions similar to those of cadmium yellow.
  • Red lead (minium) (inorganic):
Darkens to black or deep brown, sometimes with a silvery sheen, when light causes formation of brown PbO2; can use hydrogen peroxide to convert darkened surface pigment to thin translucent film of white sulphate which allows red beneath to show through. (see white lead, above).
  • Vermillion (red mercuric sulphide) (red cinnabar) (inorganic): "... its easy redissolution, must be approached with great circumspection if washing in water is contemplated as treatment." (Cohn - AIC - p. 39-40)
May darken toward black with sun exposure, which promotes conversion to the black enantimorph (meta- cinnabar). Darkening occurs more with artificial pigment. Some say that this discoloration is reversible to a certain extent in the dark.
  • Yellows
  • Gamboge (organic):
  • A gum resin so is partially soluble in alcohol and some other organic solvents.
  • Is alkali sensitive. Discolors to red with alkali. Darkens with ammonia fumes.
  • Fades in sunlight.
  • Its use in a watercolor may be revealed only after the closest examination, for it was recommended not only as a pigment but as a local varnish, to intensify the tones of deep green and brown foliage areas, where its coloring effect would be inconsequential.” (Cohn-AIC-p. 40)
  • In 19th c. is often mixed with Prussian blue to produce a green. It may pass unnoticed in testing prior to treatment but may solubilize in solvent treatment, changing green to blue.
  • Yellow Lake (Quercitron Lake, Brown Pink) (organic):
Fades to bluish gray or yellowish brown on contact with alkalis.
  • Indian Yellow (organic):
Discolors to brown on decomposition by oxidation, hydrolysis.
  • Lead-tin yellow (inorganic):
Discolors to grey, i.e. may revert to white lead on long exposure to damp air.
Blackens to lead sulphide in presence of hydrogen sulphide.
  • Orpiment (inorganic):
Blackens when placed with copper containing pigments, forming black copper sulphide.
  • Naples Yellow (inorganic):
Blackens or darkens in the presence of sulphur compounds (in air or in other pigments), or when in contact with metallic iron, tin, pewter, zinc.
  • Turner's Patent Yellow (inorganic):
Blackened by water and sunlight.
  • Chrome Yellow (inorganic):
Turns green when mixed with colors of organic origin: tendency towards reduction, the loss of oxygen by its chromic constituent, by which the green oxide of chromium is formed.
Darkens to dark brown or grey on reaction with hydrogen sulphate in polluted air.
  • Barium Yellow (inorganic):
Turns green on exposure to light due to formation of chromic oxide.
  • Cadmium Yellow (inorganic):
Bleached by water and oxygen from atmosphere due to formation of white cadmium hydroxide.
Darkens when mixed with copper piments or when mixed with flake white, the lead of the latter takes a sulphur ion from the cadmium yellow, transforming it to black lead sulphide.
  • Cobalt Yellow (aureolin) (inorganic): Discolors to brown or black when mixed with indigo in presence of hydrogen sulphide.
  • Greens
  • Copper greens
Malachite (basic copper carbonate)
Green verditer (manufactured basic copper carbonate)
Verdigris (copper acetate) Copper resinate (copper acetate or other copper salt in resinous solution)
  • Degradative effects on paper
("Kupferfrass") (verdigris, copper resinate)
  • Appearance: "During the first stage pigments seem to migrate to the reverse of the paper support giving it a green appearance. In the following stage the paper becomes brownish, first locally at those places bearing the green pigment; afterwards the destruction spreads over wider areas. As the browning increases, the green color disappears gradually and in extreme cases cannot be detected anywhere. Finally the perforation of the paper takes place on account of its increase embrittlement" (Mairinger et. al.-p. 181)
  • Causes: "IRS studies concerning degradative properties of some copper compounds with cellulose gave indications for combined influence of SO2 and sunlight with wavelengths above 330–340 nm.” (Banik and Ponahol-p. 1)
  • Specific pigments: "Different types of copper acetate showed no uniform behaviour but gave stronger effects than copper chloride, whereas malachite, schweinfurt green and calcium-copper acetate were proved to be inert, as far as the present research work could be carried out." (Banik and Ponahol - p. 1)
  • Alteration in pigment hue: "Discolorations ranging from small shifts of hue to a complete change from green to brown or even to black..." (Mairinger et. al.-p. 180. See article for discussion of chemical reactions).
  • Treatments
  • The literature mentions that soluble magnesium, calcium, cadmium salts inhibit decomposition of cellulose by heavy metal ions. Tests by Mairinger et. al indicate that "Magnesium seems to inhibit strongly the degradation of the paper carrier." Chelating and complexing agents might be used for the same purpose. (Mairinger et.al.-p. 181)
Question remains as to how much magnesium is needed.
Caution must be taken if the area is very acidic, as alkali may be injurious. (J.K.)
  • Scheele's Green: Rapid fading, blackening due to decompostion by acids, presence of lead; also, blackening due to formation of copper sulphide in presence of sulphur containing air.
  • Emerald Green: Turns brown or black in strong light, in presence of sulphur containing air or pigments, or when decomposed by acids or warm alkalis.
  • Sap Green: Fades.
  • Hooker's Green (Prussian Blue and Gamboge): Turns blue due to fading of gamboge.
  • Chrome Green (Prussian Blue and Chrome Yellow): Turns blue in strong light, due to darkening of chrome yellow or because of acids which dissolve lead chromate.
Turns dark orange in alkalis which effect the decomposition of the Prussian Blue component.
  • Blues
  • Indigo (organic):
Vegetable coloring matter. May undergo discoloration by reduction reactions. i.e. turns white when reduced by any of several reducing agents to soluble indigo white, which is oxidized by air to insoluble indigo blue. Also, bleached by hypochlorite solutions.
Fading or browning when decomposed by photooxidation; fading increased by presence of alum in the paper.
  • Logwood: (organic): Used in 17th and early 18th c. to color prints.
Discolors to red.
  • Prussian blue (organic): Alkali sensitive may turn brown. Fades in strong light. Literature mentions that depth of blue will return after brief storage in the dark.
Treatment: some suggestion that unanticipated browning of Prussian blue exposed to alkaline material during treatment might be reversed by exposure to mild acid, i.e. carbonic acid formed by carbon dioxide reacting with moisture. In practice the material might be humidified/moistened and exposed to the air. (A.O.)
  • Ultramarine (natural and synthetic) (inorganic): Turns pale greyish blue when decomposed by very weak acids and the presence of sulphur dioxide.
"Acid sensitive." Will permanently decolorize, e.g. if a picture with a slat burn is treated with water, making the acid liquid. (M.C.)
  • Azurite: (inorganic): Turns green by hydration.
Blackened by warm alkalis or exposure to sulphur fumes.
  • Blue Verditer (inorganic): Turns green through loss of ammonia component.
  • Smalt (inorganic): Turns pale greyish from exposure to moisture and carbonic acid in air.

Cautions for paints during conservation treatment.

Miscellaneous Media

Wax

Can be applied to paper in the form of drips (Jackson Pollack) or brushed on as resist (Victor Brauner). In both cases, it was observed that the paper below the wax darkened and became brittle. The same guidelines for painting in oil on paper apply to the use of wax. (M.E.)

Sargent used white wax resist pencil in some watercolors. (M.C.)

Distemper

On early wallpaper may be insoluble but friable. Particles may physically be moved by touch or water. (J.K.)

Vuillard used dry pigments and warm glue, “detrempe,” on paper. One such painting was seen to have severe flaking problems. Literature mentions that Vuillard had flaking problems even while he was working. (M.E.)

Enamel

Jackson Pollack used enamel for some of his drip paintings on paper. The paper below these enamel lines is severly degraded - brown, brittle, and in several cases, cracked. Suspicion that this early type of enamel was nitrocellulose. Pollock preferred it because it dried quickly. (M.E.)

Mixed media

  • Acrylic mixed with gouache, e.g. Altoon
  • Foodstuffs combined with traditional media, e.g. Rusche, Rauschenberg

Prints and Printing Inks

General considerations about stability and permanence:

  • Solubility: printing inks are generally insoluble in water and most organic solvents. There are, however, exceptions. Inks which appear safely insoluble in a given solvent during preliminary testing may soften or begin to bleed during actual treatment, prolonged treatment or reimmersion. One soluble component of an ink may be released onto the paper or into a bath, or in rare cases the entire ink may soften or solublize. See Washing
  • Contemporary and modified formulations: from the mid nineteenth century on printing ink formulations become more experimental and brief spot tests become less reliable in predicting the stability of these inks towards immersion in water, alkaline baths, or solvents.
  • Breakdown of binder: "In some black and white prints, esp. 19th [c.] prints where the blacks are heavily applied, the oil medium appears to have disintegrated and the black pigment lies like chalk on the surface. Obviously these should not be placed in a water bath." (Weidner)
  • Alkaline reactions: Some fear that very alkaline solutions may saponify the oil in printing inks, causing the binder to break down.
Have seen oil paint stains on the verso of a drawing which had been stable for 100 years saponify after deacidification and stain through the sheet. (M.C.)
Consideration might be given to introducing the print first into a neutral water bath and gradually increasing the alkalinity of subsequent baths, thus avoiding possible damage to the oil binder. (L.K.)
  • If a component of a printing ink is softened or solubilized during treatment: the conservator can be faced with a split second decision:
  • Is it safest to allow the soluble component to bleed out into the bath, hopefully resulting in little apparent visual alteration of the ink and lessening the likelihood that the solubilized component will be set permanently, remaining as a disfigurement on the paper support, or
  • is it safer to immediately remove the object from the bath and treat the bleeding component locally, possibly on the suction table, or blot and blow dry?
  • When the softening/solubility is overall, clearly immediate removal from the bath is dictated.
  • Storage Problems:
  • Reported softening of lithograph and engraving inks on prints stored for several years in fresh cedar shelving.
  • Urea formaldehyde adhesive in plywood may effect media. Air circulation important in storage areas constructed of plywood.

Intaglio

  • Engraving (line, stipple, copperplate, steel)
  • Mezzotint: more friable ink surface than other intaglio techniques. Especially fragile as soap was added to enhance impression quality.
  • Drypoint:
  • Etching: (regular, crayon, soft-ground, sugar-lift, relief, aquatint)


Planographic

  • Lithograph (crayon, chalk, pen, wash, litho-engraving, litho-etching, litho-mezzotint, chromo-litho)
Red inks on chromolithographs can split and bleed. Deacidification can make the problem worse. Length of time in a bath can be critical (Calder, Toulouse Lautrec, movie posters: 1930s and 1940s).
  • Offset lithograph


Relief: (woodcut, metalcut, chiaroscuro woodcut, wood engraving, linoleum print, letter press, zinc etching (relief etching), white engraving on stippled background.

  • 20th century woodcuts: reported pale tinted material bleeding out from inks in early 20th century woodcuts in water baths (Provincetown School, Russian Constructivist). The green ink on a Heckel woodcut split and bled yellow to the verso of the print, so caution with German Expressionists as well.
  • Some late 19th early 20th c. woodcuts are printed with paste binder ink “a la Japonnaise.”


Stencil

  • Screenprint (formerly silkscreen)
Soft, matte surface is extremely vulnerable to burnishing, even by cover tissue dragged casually across the face.
Silkscreen prints by Robert Motherwell, framed with plexiglas, developed white powdery accretions both on the surface of the print and on the plexiglas where the two came into contact. It is assumed that this was a reaction between the plexiglas and the silkscreen inks.
  • Pochoir
Teriade used Linel paints for Matisse's Jazz series: very water soluble and very susceptible to abrasion. Some colors also solvent soluble (e.g. acetone).


Hand colored prints

Hand coloring may remain soluble

Varnished or glazed prints "On some prints, in order to heighten a dark color, a thin transparent, varnish like coating is applied to a print, often in a haphazard fashion. This appears to be either a gum resin or gelatin. It is easily water soluble and sometimes becomes crackled, like a varnish on an oil painting and starts flaking off, taking the ink and color beneath with it. This has been noted particularly on Currier and Ives, racing prints and Daumier prints." (Weidner)

The varnish or glaze is often an important part of the history of the print.

Japanese woodcuts

Colors are derived largely from vegetable sources and are highly impermanent.

  • Fugitive: e.g. aigami blue, beni pink, yukon yellow
  • Soluble
  • Mica
  • Metallic “inks” (brass, tin, silver) often tarnish.


Photomechanical prints

  • Planographic: (collotype, Albertype, heliotype, photolithography/photchrome, offset)
  • Relief: (wood engraving and zinc relief, swell gelatin or levytype, line cut photo engraving: half tone, fourcolor process, Woodburytype or gravure, photomezzotint, stannotype).


Photoelectric (photocopy) (copy art) (transfer photocopy, direct photocopy, color photocopy, color and color photocopy)

Other

  • Thermography (pseudo embossing): powdered resinous material is blown across the wet printing ink and fused with heat. This gives it a raised character which imitates engraving; often in letterheads. Reportedly, the resinous binder in some formulations may soften and dissolve in solvents (e.g. acetone), leaving behind only the loose raised ink deposit on the surface.
  • Computer art
  • Monotype
  • Collagraph

Media Identification Websites


Image Permanence Institute's Graphics Atlas
The Philadelphia Museum's Descriptive Terminology for Works of Art on Paper

Bibliography


Arney, J.S., A. J. Jacobs, and R. Newman. 1979. "The Influence of Oxygen on the Fading of Organic Colorants." Journal of the American Institute for Conservation" 18(2): 108-117. Accessed May 18, 2020.

Banik, Gerhard and Johann Ponahol. 1982. "Some Aspects Concerning Degradation Phenomena of Paper Caused by Green Copper Containing Pigments." The Paper Conservator 7: 3-7.

Banik, Gerhard, H. Stachelberger and O. Wachter. 1982. "Investigation of the destructive action of copper pigments on paper and consequences for conservation." IIC Preprints of the Contributions to the Washington Congress 1982. Washington D.C. 75-78.

Blythe, Victoria S. 1978. "Electrostatic Stablilizing Plate (E.S.P.): An Alternative Method for Stablilizing the Flaking Tendencies of Works of Art in Pastel." In ""The American Institute for Conservation of Historic and Artistic Works Preprints, Sixth Annual Meeting. Washington DC: AIC 21-30.

Brommelle, N. 1964. "The Russell and Abney Report on the Action of Light on Water Colours." Studies in Conservation 9(4): 140-152. Accessed May 18, 2020.

Brunner, Felix. 1962. A Handbook of Graphic Reproduction Processes. Switzerland : Arthur Nigli Ltd.

Burgess, Helen, and Charlette, C.L. 1981. "Aspects of Image Safety in the Use of Enzymes in Paper Conservation." In Preprints of 6th Triennial Meeting Ottawa 1981. Paris : International Council of Museums Committee for Conservation.

Burgess, Helen, and Charlette, C.L. 1983. "The Use of Fixatives to Protect Fugitive Colourants During Conservation Treatments. In Preprints of Papers Presented at the Eleventh Annual Meeting, Baltimore Maryland, 25-29 May 1983. Washington DC : American Institute for Conservation of Historic and Artistic works. 129-139.

Cennini, Cennino d'Andrea. 1960. The Craftsman's Handbook. Translated by Daniel V. Thompson, Jr. New York : Dover Publications.

Cohn, Marjorie B. 1977. Wash and Gouache. A Study of the Development of the Materials of Watercolor. Cambridge, Massachusetts : Center for Conservation and Technical Studies, Fogg Art Museum.

Cohn, Marjorie B. 1977. Wash and Gouache: Watercolor at Harvard. Preprints of papers presented at the fifth annual meeting of the AIC, Boston, Mass., 30 May - 2 June 1977. Washington DC : American Institute for Conservation. 35-40.

Costicova, E. A. 1978. The Regeneration of Colour of the Darkened Lead White by Method of Absorption of Hydrogen Peroxide Vapors. In ICOM Committee for Conservation. 5th Triennial Meeting, Zagreb, 1 - 8 Oct. 1978: Preprints. Paris : The International Council of Museums.

Daniels, Vincent. 1982. "Colour Changes of Watercolour Pigments During Deacidification." In Science and Technology in the Service of Conservation: Preprints of the Contributions to the Washington Congress, 3-9 September 1982. International Institute for Conservation of Historic and Artistic Works. 66-70.

Doerner, Max. 1962. "Painting in Watercolors" and "Pigments." In The Materials of the Artist and Their Use in Painting: With Notes on the Techniques of the Old Masters. New York : Harcourt, Brace and World.

Ellis, Margaret Holben. 1979. "Charcoal, Chalk, and Pastel Drawings - Special Problems for Collectors: Parts 1 and 2." Drawing 1(3-4): 56-58, 79-80.

Ellis, Margaret Holben. 1979. "A Conservation Checklist for Drawings Collectors." Drawing 1(2): 29-32.

Ellis, Margaret Holben. 1980. "Metalpoint Drawings: Special Conservation Problems for Collectors." Drawing 2(3): 59-61.

Ellis, Margaret Holben. 1980. "Watercolors: Special Conservation Problems for Collectors." Drawing 1(5): 101-102.

Evans, Debra. 1978. "Color Change in Watercolor Pigments." Typescript of talk given at Winterthur; literature survey on the nature and causes of discoloration of specific pigments.

Fairbrass, Sheila. 1984. "The Problem of Copy Pencil in Works of Art on Paper." The Conservator 8(1): 8-9.

Feller, Robert L. 1967. "Studies in the Darkening of Vermillion by Light." Report and Studies in the History of Art 1: 99-111.

Feller, Robert., Mary Curran and Catherine Bailie. 1984. "Identification of Traditional Organic Colorants Employed in Japanese Prints and Determination of their Rates of Fading." In Japanese Woodblock Prints: A Catalogue of the Mary A. Ainsworth Collection. Oberlin, Ohio : Allen Memorial Art Museum.

Flieder, Francois. 1983. "Study of the Conservation of Pastels." Science and Technology in the Service of Conservation: Preprints of the Contributions to the Washington Congress. 71-74.

Gettens, Rutherford J., and George Stout. 1966. "Painting Materials: A Short Encyclopedia." New York : Dover Publications, Inc.

Haner, Paul, Quentin Rankin and Timothy Vitale. 1980. "Paintings on Paper: A Dialogue in Five Case Histories." In Preprints of Papers Presented at the Eighth Annual Meeting, San Francisco. Washington DC : American Institute for Conservation. 26-38.

Harding, Eric. 1983. "Restoration of Drawings Executed on Prepared Paper." The Conservator 7(1): 24-28.

Harley, Rosamond D. 1982. Artist's Pigments c. 1600 - 1835: A Study in English Documentary Sources. New York : American Elsevier Publishing Co.

Hey, Margaret. 1977. The Deacidification and Stabilization of Iron Gall Inks-Cellulose Combinations on Paper. In Proceedings of the Fifth Annual Meeting of AIC, Boston. Washington, DC : AIC.

Lerwill, Andrew, Joyce H. Townsend, Jacob Thomas, Stephen Hackney, Charlotte Caspers, and Haida Liang. 2015. "Photochemical colour change for traditional watercolour pigments in low oxygen levels." Studies in Conservation 60(1): 15-32.

An article that sampled a very wide range of pigments with detailed tables and graphs to record the results. Most pigments benefitted from anoxia storage, except for Prussian blue and green. Storage in <5% oxygen is proposed for ‘anoxic’ display of paper-based artworks that might contain Prussian blue.

Johnston-Feller, Ruth, Robert L. Feller, Catherine W. Bailie and May Curran. 1983. "Kinetics of the Fading of Alizarin Lake." In AIC Preprints. American Institute for Conservation 11th Annual Meeting, Baltimore. Washington, DC : AIC. 65-73.

Korenberg, Capucine. 2008. "The photo-ageing behaviour of selected watercolour paints under anoxic conditions." The British Museum Technical Research Bulletin 2: 49-57. Accessed May 22, 2020.

Many objects deteriorate faster in the presence of oxygen, so some are chosen to be displayed in anoxic cases. However, it is important to note whether the pigments are affected by these conditions. Alzarin crimson, chrome deep, realgar, Alizarin crimson, orpiment, Prussian blue and Antwerp blue, were tested. Conclusions are that Prussian and Antwerp blue should not be placed under anoxic conditions, while alizarin crimson and orpiment faded considerably less under anoxic conditions. Antwerp blue faded considerably more than Prussian blue in airtight conditions.

Laurie, A.P. 1967. The Painter's Methods and Materials. NY : Dover Publications, Inc. Chapter 6: The Pigments used in Painting.

Mairinger, Franz, Gerhard Banik, Herbert Stachelberger, Alfred Vendl, and Johann Ponahlo. 1980. "The Destruction of Paper by Green Copper Pigments, Demonstated by a Sample of Chinese Wallpaper." In Conservation Within Historic Buildings: Preprints of the Contributions to the Vienna Congress.

Matteini, Mauro, and A. Moles. 1981. "The Reconversion of Oxidized Lead White in Paintings: A Control After a Five Year Period." ICOM Committee for Conservation preprints. 6th Triennial Meeting, Ottawa. Paris : ICOM.

Mayer, Ralph. 1970. The Artist's Handbook of Materials and Techniques, 3rd. ed. NY: Viking Press.

McGee, Julie L., Jessica Silverman, and Amy Heuer. 2016. “Conserving Hermes Trigmegistus & African Rainbow.” Tru Vue Newsletter.

Two very large pastel drawings on paper by artist Amos Ashanti Johnson were treated. The pastels presented mold growth, tape damage and cockling of the surface of the paper due to frames that were too small. The planar distortion meant that the pigments were in contact with the glass in the frame, and the pigments were transferring the glass. Silverman removed the mold using pointed bamboo skewers dipped in an acrylic adhesive that remains tacky at room temperature. The article does not name the adhesive that was used. The tape was removed using a heated spatula. When the pastels were framed, a spacer was placed so that there was a gap between the glass and the pastel. A gutter was also devised at the bottom of the image, so that any loose pigment could be collected.

Perkinson, Roy. 1974. "On Conservation: Lighting Works of Art on Paper." Museum News 53(3): 5-7.

Prochazka, M., M. Palece, and F. Martinek. 1978. "Procedures for Making Traces of Iron Gallotannate Writing More Perceptible." Restaurator 2(3). Accessed May 26, 2020.

Stachelberger, Herbert and Gerhard Banik. 1984. "The Intermicroscopic Correlation (LM, SEM) of Cross-Sections of Writing Materials." ICOM Committee for Conservation preprints. 7th triennial meeting, Copenhagen." Paris : ICOM. 44-46.

span id="refTalbotFlieder1978">Talbot, Roseline, Francoise Leclerc and Francoise Flieder. 1978. "Etude de la Regeneration Chinique des Encres Metallo-Galliques." ICOM Committee for Conservation preprints. 5th Triennial Meeting, Zagreb. Paris: ICOM.

Thompson, Gary. 1978. The Museum Environment. Boston : Butterworths.

With reference to the effects of general environment, light, pollution, humidity on works of art on paper.

Watrous, James. 1957. The Craft of Old Master Drawings. Madison, Wisconsin: The University of Wisconsin Press.

Weidner, Marilyn. 1970. Conservation of Art on Paper. Unpublished information sheet for a lecture at the Regional Meeting of the American Association of Museums.

Welsh, Elizabeth C. 1980. "A Consolidation Treatment for Powdery Matte Paint." In ” In AIC Preprints. American Institute for Conservation 8th Annual Meeting, San Francisco. Washington, DC : AIC. 141-150. Accessed May 26, 2020.

History of This Page


BPG Wiki
In 2009, the Foundation for Advancement in Conservation (FAIC) launched the AIC Wiki with funding assistance from the National Center for Preservation Technology and Training (NCPTT), a division of the National Parks Service. Along with catalogs from other specialty groups, the published Paper Conservation Catalog and the unpublished Book Conservation Catalog were transcribed into a Wiki environment. In 2018, Jennifer Evers reformatted this page by removing the legacy numbered outline format and improving internal links.

Paper Conservation Catalog (print edition 1984-1994)
Prior to the creation of the AIC Conservation Wiki, this page was created in 1985 as Chapter 3: Media Problems of the 2nd edition of the Paper Conservation Catalog, (print edition 1984-1994) by the following:

Compiler: Nancy Ash
Contributors: Bob Aitchison, Victoria Blythe-Hill, Craigen Weston Bowen, Marjorie Cohn, Pia De Santis, Margaret Ellis, Karen Garlick, John Krill, Leslie Kruth, Meredith Mickelson, Kitty Nicholson, Antoinette Owen, Joanne Page, Linda Schaffer, Mark Watters


Book and Paper Group Wiki
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Preservation

·Selection for Preservation ·Exhibition, Supports, and Transport ·Imaging and Digitization ·Housings ·Encapsulation ·Integrated Pest Management (AIC) ·Environmental Guidelines (AIC) ·Environmental Monitoring (AIC) ·Agents of Deterioration (AIC) ·Light Levels (AIC) ·Pollutants and Contaminants (AIC) ·Emergency Preparedness & Response (AIC)

Conservation History and Ethics

·AIC Code of Ethics and Guidelines for Practice ·Culturally Sensitive Treatment ·Conservation Ethics (AIC) ·History of Conservation and Conservators (AIC) ·History of the BPG Wiki